TY - BOOK AU - Wang,Zhandong ED - SpringerLink (Online service) TI - Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion T2 - Springer Theses, Recognizing Outstanding Ph.D. Research, SN - 9789811056932 AV - TJ265 U1 - 621.4021 23 PY - 2018/// CY - Singapore PB - Springer Singapore, Imprint: Springer KW - Thermodynamics KW - Heat engineering KW - Heat transfer KW - Mass transfer KW - Air pollution KW - Physical chemistry KW - Engineering Thermodynamics, Heat and Mass Transfer KW - Atmospheric Protection/Air Quality Control/Air Pollution KW - Physical Chemistry N1 - Acceso multiusuario; Introduction -- Experimental method and kinetic modeling -- Experimental and modeling study of cyclohexane combustion -- Experimental and modeling study of methylcyclohexane combustion -- Experimental and modeling study of ethylcyclohexane combustion -- Combustion kinetics of cyclohexane and C1-C2 mono-alkyl cyclohexanes -- Conclusions and perspective N2 - This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes' combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control UR - http://148.231.10.114:2048/login?url=https://doi.org/10.1007/978-981-10-5693-2 ER -