000			05274nam a22005415i 4500
001			u373080
003			SIRSI
005			20160812084129.0
007			cr nn 008mamaa
008			100427s2010 au | s |||| 0|eng d
020			_a9783211929483 _9978-3-211-92948-3
040			_cMX-MeUAM
050		4	_aQC173.4.A87
050		4	_aQD461
082	0	4	_a539 _223
100	1		_aEaton, Gareth R. _eauthor.
245	1	0	_aQuantitative EPR _h[recurso electrónico] : _bA Practitioners Guide / _cby Gareth R. Eaton, Sandra S. Eaton, David P. Barr, Ralph T. Weber.
264		1	_aVienna : _bSpringer Vienna : _bImprint: Springer, _c2010.
300			_aXII, 185 p. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
505	0		_aIntroduction -- Principles of Quantitative EPR; Why should examples of applications be quantitative?; Examples of applications -- Introduction to Quantitative EPR; General expression for CW EPR signal intensity; The EPR transition; Derivative spectra; The CW EPR line width; Second derivative operation; What transitions can we observe; Features of transition metal EPR; Parallel and perpendicular transitions -- Getting started- some practical matters; Operating the spectrometer-cautionary notes; Sample preparation; Don´t forget the cooling water!; Detector current; Automatic frequency control and microwave phase; Searching for a signal; Gain; Effect of scan rates and time constants on S/N and signal fidelity; bandwidth considerations; scan rate and filter time constant; selecting a non-distorting filter and scan rate; A note about comparing noise in CW and pulsed EPR; Background signals; Integration; Microwave power; Modulation amplitude; Modulation amplitude calibration; How to select modulation frequency; Modulation sidebands;Illustration of the effect of modulation amplitude, Modulation frequency, Microwave power on the spectra of free radicals; Phase; Automatic frequency control and microwave phase;Sample considerations; Passage effects; Software; Summary guidance for the operator; Scaling results for quantitative comparisons; Signal averaging; Number of data points, Cleanliness; Changing samples; NMR gaussmeter interference -- What matters, and what can you control? Crucial parameters and how they affect EPR signal intensity;What accuracy can one aspire to?- A deeper look at B1 and modulation field distribution in a resonator; Inhomogenity of B1 and modulation amplitude; Flat cells; Double-cavity simultaneous reference and unknown.-Resonator Q; Conversion efficiancy, C; Contributions to Q; Measurement of Resonator Q -- Filling factor. Temperature; Intensity vs. temperature; Practical example; Glass-forming solvents; Practical aspects of controlling and measuringsample temperature; Operation above room temperature.-Magnetic field and Microwave frequency;G-values; Microwave frequency; Magnetic field; Magnetic field homogenity; Coupling constants vs. hyperfine splittings.-Standard samples; Comparison with a standard sample; Standard samples for Q-band; Achievable accuracy and precision- g value and hyperfine splitting -- How good can it get?- Absolute EPR signal intensities; The spin magnetization M for an arbitrary spin S; Signal voltage; Calculation of noise; Calculation of S/N; Summary of impact of parameters on S/N; How to improve the spectrometer-the Friis equation -- Less common measurements with EPR spectrometers; Multiple resonance methods; Saturation transfer spectroscopy; Electrical conductivity; Static magnetization.
520			_aThis is the first comprehensive yet practical guide for people who perform quantitative EPR measurements. No existing book provides this level of practical guidance to ensure the successful use of EPR. There is a growing need in both industrial and academic research to provide meaningful and accurate quantitative EPR results. This text discusses the various sample, instrument and software related aspects required for EPR quantitation. Specific topics include: choosing a reference standard, resonator considerations (Q, B1, Bm), power saturation characteristics, sample positioning, and finally, putting all the factors together to obtain an accurate spin concentration of a sample.
650		0	_aPhysics.
650		0	_aChemistry.
650		0	_aChemistry, Physical organic.
650		0	_aBiochemistry.
650		0	_aSurfaces (Physics).
650	1	4	_aPhysics.
650	2	4	_aAtomic/Molecular Structure and Spectra.
650	2	4	_aCharacterization and Evaluation of Materials.
650	2	4	_aBiochemistry, general.
650	2	4	_aBiophysics and Biological Physics.
650	2	4	_aPhysical Chemistry.
650	2	4	_aChemistry/Food Science, general.
700	1		_aEaton, Sandra S. _eauthor.
700	1		_aBarr, David P. _eauthor.
700	1		_aWeber, Ralph T. _eauthor.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783211929476
856	4	0	_zLibro electrónico _uhttp://148.231.10.114:2048/login?url=http://link.springer.com/book/10.1007/978-3-211-92948-3
596			_a19
942			_cLIBRO_ELEC
999			_c200960 _d200960